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Nitrous acid (molecular formula HNO2) is a weak and monobasic acid known only in solution and in the form of nitrite salts.
Nitrous acid is used to make diazides from amines; this occurs by nucleophilic attack of the amine onto the nitrite, reprotonation by the surrounding solvent, and double-elimination of water. The diazide can then be liberated as a carbene.
Additional recommended knowledge
Nitrous acid can be prepared by adding any mineral acid to sodium nitrite.
Nitrous acid rapidly decomposes into nitrogen dioxide, nitric oxide, and water when in solution.
2HNO2 → NO2 + NO + H2O
It also decomposes into nitric acid and nitrous oxide and water.
4HNO2 → 2HNO3 + N2O + H2O
Nitrous acid is used to prepare diazonium salts:
Such salts are widely is used in organic synthesis, e.g., for the Sandmeyer reaction and in the preparation azo dyes, brightly-colored compounds that are the basis of a qualitative test for anilines. Nitrous acid is used to destroy toxic and potentially-explosive sodium azide. For most purposes, nitrous acid is usually formed in situ by the action of mineral acid on sodium nitrite:
Nitrous acid is an important atmospheric intermediate. It is produced by the heterogeneous reaction of NO2 and water on various surfaces such as atmospheric aerosols. It is readily photolysed to produce hydroxyl radicals, which are intricately involved in the ozone budget of the troposphere (lower atmosphere).
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Nitrous_acid". A list of authors is available in Wikipedia.|