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Quaternary ammonium cation
Additional recommended knowledge
Quaternary ammonium cations, also known as quats, are positively charged polyatomic ions of the structure NR4+ with R being alkyl groups. Unlike the ammonium ion NH4+ itself and primary, secondary, or tertiary ammonium cations, the quaternary ammonium cations are permanently charged, independent of the pH of their solution. Quaternary ammonium cations are synthesized by complete alkylation of ammonia or other amines. For possible synthesis route, see amines.
Quaternary ammonium salts or quaternary ammonium compounds are salts of quaternary ammonium cations with an anion. They are used as disinfectants, surfactants, fabric softeners, and as antistatic agents (e.g. in shampoo). In liquid fabric softeners, the chloride salts are often used. In dryer anticling strips, the sulfate salts are often used. This is also a common ingredient in many spermicidal jellies.
In organic chemistry, quaternary ammonium salts are used as phase transfer catalysts for reactions involving immiscible solvent systems, such as the synthesis of dichlorocarbenes with chloroform and sodium hydroxide.
The synthesis of this cation from ammonia is referred to as quaternization.
Through exhaustive methylation, or the Hofmann Elimination process, a quarternary ammonium iodide salt is formed. The alpha-carbon (relative to the nitrogen) is deprotonated once by a hydroxide anion from H2O and the electrons form an alkene. Subsequently, the electrons from the carbon-nitrogen bond are pushed onto the nitrogen. This sets up a tertiary amine as the leaving group.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Quaternary_ammonium_cation". A list of authors is available in Wikipedia.|