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Polychlorinated biphenyl


Polychlorinated biphenyls (PCBs) are a class of organic compounds with 1 to 10 chlorine atoms attached to biphenyl which is a molecule composed of two benzene rings each containing six carbon atoms. The chemical formula for all PCBs is C12H10-xClx.

PCBs were used as coolants and insulating fluids for transformers and capacitors, stabilizing additives in flexible PVC coatings of electrical wiring and electronic components, pesticide extenders, cutting oils, flame retardants, hydraulic fluids, sealants, adhesives, paints, de-dusting agents, and in carbonless copy paper.[1]

PCB production was banned in the 1970s due to the high toxicity of most PCB congeners and mixtures. PCBs are classified as persistent organic pollutants which bioaccumulate in animals.



Physical and chemical properties

PCB congeners are odorless, tasteless, clear to pale-yellow, viscous liquids. They are formed by electrophilic chlorination of biphenyl with chlorine gas. There are theoretically 209 different PCB congeners, although only about 130 of these were used in commercial PCBs.[2] Commercial PCBs are mixtures of 50 or more PCB congeners.[2] Commercial PCB mixtures are clear to pale-yellow, viscous liquids (the more highly chlorinated mixtures are more viscous and more yellow, for example, Aroclor 1260 is a sticky yellowish resin). PCBs have low water solubilities — 0.0027-0.42 ng/L for Aroclors,[1] and low vapor pressures at room temperature, but they have high solubilities in most organic solvents, oils, and fats. They have high dielectric constants, very high thermal conductivity,[1] high flash points (170-380°C)[1] and are chemically almost inert being extremely resistant to oxidation, reduction, addition, elimination, and electrophilic substitution.[3] The density varies from 1.182 to 1.566 kg/L.[1] Other physical and chemical properties vary widely across the class. As the degree of chlorination increases, melting point and lipophilicity increase, but vapour pressure and water solubility decrease.[1]

PCBs readily penetrate skin, PVC (polyvinyl chloride), and latex (natural rubber); organic solvents such as kerosene increase the rate of skin absorption.[4] PCB-resistant materials include Viton, polyethylene, polyvinyl acetate (PVA), polytetrafluoroethylene (PTFE), butyl rubber, nitrile rubber, and Neoprene.[4]

PCBs are very stable compounds and do not degrade readily. They may be destroyed by chemical, thermal, and biochemical processes, though it is extremely difficult to achieve full destruction, and there is the risk of creating extremely toxic dibenzodioxins and dibenzofurans through partial oxidation. Because of the high thermodynamic stability of PCBs, all degradation mechanisms are difficult to sustain. Intentional degradation as a treatment of unwanted PCBs generally requires high heat or catalysis. Environmental and metabolic degradation generally proceeds quite slowly relative to most other compounds.

Alternative names

Commercial PCB mixtures were marketed as Clophen by Bayer in Germany, Aroclor by Monsanto in USA, Kanechlor by Kanegafuchi in Japan, Santotherm by Mitsubishi in Japan, and Phenoclor and Pyralene by Prodolec in France.[1]


PCBs were commercially produced as complex mixtures containing multiple isomers at different degrees of chlorination. In the United States, commercial production of PCBs was taken over in 1929 by Monsanto from Swann Chemical Company. Manufacturing levels increased in response to the electrical industry's need for a "safer" cooling and insulating fluid for industrial transformers and capacitors. PCBs were also commonly used as stabilizing additives in the manufacture of flexible PVC coatings for electrical wiring and electronic components to enhance the heat and fire resistance of the PVC.[5]

PCBs are persistent organic pollutants and have entered the environment through both use and disposal. The environmental transport of PCBs is complex and nearly global in scale. The public, legal, and scientific concerns about PCBs arose from research indicating they were likely carcinogens having the potential to adversely impact the environment and therefore undesirable as commercial products. Despite active research spanning five decades, extensive regulatory actions, and an effective ban on their production since the 1970s, PCBs still persist in the environment and remain a focus of attention.[1]

The only North American producer, Monsanto, marketed PCBs under the trade name Aroclor from 1930 to 1977. These were sold under trade names followed by a 4 digit number. The first two digits generally refer to the number of carbon atoms in the biphenyl skeleton (for PCBs this is 12), the second two numbers indicate the percentage of chlorine by mass in the mixture. Thus, Aroclor 1260 has 12 carbon atoms and contains 60% chlorine by mass. An exception is Aroclor 1016, which also has 12 carbon atoms, but has 42% chlorine by mass. Different Aroclors were used at different times and for different applications. In electrical equipment manufacturing in the USA, Aroclor 1260 and Aroclor 1254 were the main mixtures used before 1950, Aroclor 1242 was the main mixture used in the 1950s and 1960s until it was phased out in 1971 and replaced by Aroclor 1016.[1]

PCB mixtures have been used for a variety of applications, including dielectric fluids for capacitors and transformers, heat transfer fluids, hydraulic fluids, lubricating and cutting oils, and as additives in pesticides, paints, carbonless copy ("NCR") paper, adhesives, sealants, plastics, reactive flame retardants, and as a fixative for microscopy. They were also used in surgical implants.

Manufacture peaked in the 1960s, by which time the electrical industry had lobbied the U.S. Congress to make them mandatory safety equipment, knowing all the while that they were extremely toxic[citation needed]. In 1966, they were determined by Swedish chemist Dr. Soren Jensen to be an environmental contaminant, and it was Dr. Jensen, according to a 1994 article in Sierra, who named them. Previously, they had simply been called "phenols" or referred to by various trade names, such as Aroclor, Kennechlor, Pyrenol, Chlorinol and others. Arochlors (chlorinated biphenyls) were known toxins in 1947. Robert Brown reminded chemists in 1947 that Arochlors were "objectionably toxic. Thus the maximum permissible concentration for an 8-hr. day is 1 mg. per cu.m. of air. They also produce a serious and disfiguring dermatitis."[6]

Their commercial utility was based largely on their chemical stability, including low flammability, and desirable physical properties, including electrical insulating properties. Their chemical and physical stability has also been responsible for their continuing persistence in the environment, and the lingering interest decades after regulations were imposed to control environmental contamination.

In 1972, PCB production plants existed in Austria, then Federal Republic of Germany, France, Great Britain, Italy, Japan, Spain, USSR, and USA.[1]

From 1973 the use of PCBs was banned in "open" or "dissipative" sources, such as:

  • plasticisers in paints and cements
  • casting agents
  • fire retardant fabric treatments and heat stabilizing additives for PVC electrical insulation
  • adhesives
  • paints and water-proofing
  • railway sleepers

However, they continued to be allowed in "totally enclosed uses" such as transformers and capacitors, which, however, tended to explode on a fairly regular basis. It was Ward B. Stone of the New York State Department of Environmental Conservation who first published his findings in the early 1970s that PCBs were leaking from transformers and had contaminated the soil at the bottom of utility poles. Concern over the toxicity and persistence (chemical stability) of PCBs in the environment led the United States Congress to ban their domestic production in 1977, although some use continues in closed systems such as capacitors and transformers.

The use of PCBs in "closed" uses include:

  • capacitors
  • insulating fluids in transformers
  • vacuum pump fluids
  • hydraulic fluids

Closed uses of PCBs were also banned in the UK from 1981, when nearly all UK PCB synthesis ceased.

In Japan, PCBs were first produced by Kanegafuchi Chemical Co. Ltd. (Kaneka) in 1954 and production continued until 1972 when the Japanese government banned the production, use, and import of PCBs.[1]

Estimates have put the total global production of PCBs on the order of 1.5 million tons. The United States was the single largest producer with over 600,000 tons produced between 1930 and 1977. The European region follows with nearly 450,000 tons through 1984. It is unlikely that a full inventory of global PCB production will ever be accurately tallied, as there were factories in Poland, East Germany, and Austria that produced unknown amounts of PCBs.[7]

Large scale environmental contamination

In the United States of America, the General Electric Company (GE) released up to 1,300,000 pounds (590,000 kg) of PCBs into the Hudson River between approximately 1947 and 1977.[8] The PCBs came from the company's two capacitor manufacturing plants at Hudson Falls and Fort Edward in New York State.[8] In 1976, because of concern over continuing high levels of PCBs in local fish and other aquatic organisms, and the unacceptable risk to the health of consumers of such fish, the New York State Department of Environmental Conservation banned all fishing in the Upper Hudson River, as well as commercial fishing of striped bass and several other species in the Lower Hudson River,[9][8] and also issued advisories restricting the consumption of fish caught within a 20-mile (30 km) long segment of the Hudson River from Hudson Falls to Troy.[8][10] There have been many programs of remediation work to reduce the PCB pollution, mostly paid for by GE. In 1984, approximately 200 miles (320 km) of the Hudson River was designated a Superfund site, and attempts to cleanup the Upper Hudson River began, including the removal in 1977-8 of 180,000 cubic yards (140,000 m³) of contaminated river sediments near Fort Edward.[9] In 1991, further PCB pollution was found at Bakers Falls near the former GE Hudson Falls factory, and a program of remediation was started.[9] In August 1995, a 40-mile (64 km) reach of the Upper Hudson was re-opened to fishing but only on a catch-and-release basis.[9] Removal of contaminated soil from Rogers Island was completed in December 1999.[9] In 2002, the United States Environmental Protection Agency announced a further 2,650,000 cubic yards (2,030,000 m³) of contaminated sediments in the Upper Hudson River would be removed.

From the late 1950s through 1977, Westinghouse Electric used PCBs in the manufacture of capacitors in its Bloomington, Indiana plant. Reject capacitors were hauled and dumped in area salvage yards and landfills. Workers also dumped PCB oil down factory drains which contaminated the city sewage treatment plant.[citation needed] The City of Bloomington gave away the sludge to area farmers and gardeners, creating anywhere from 200 to 2000 sites which remain unaddressed. Over 2 million pounds of PCBs were estimated to have been dumped in Monroe and Owen Counties, making it the biggest concentration of PCBs in the world.[citation needed] Although federal and state authorities have been working on the site remediations, many areas remain contaminated. Concerns have been raised regarding the removal of PCBs from the karst limestone topography, and regarding the possible disposal options. To date, the Westinghouse Bloomington PCB Superfund site case does not have a RI/FS (Remedial Investigation/Feasibility Study) and ROD (Record of Decision), although Westinghouse signed a US Department of Justice Consent Decree in 1985.[citation needed]

Much of the Great Lakes area is still heavily polluted with PCBs, despite extensive remediation work.[11] Locally caught fresh water fish and shellfish are contaminated with PCBs and their consumption is restricted.

PCBs have been detected globally, from the most urbanized areas that are the centers for PCB pollution, to regions north of the Arctic Circle. Typical urban atmospheric concentrations are in the picogram per cubic meter range. The atmosphere serves as the primary route for global transport of PCBs, particularly for those congeners with 1 to 4 chlorine atoms.

Health effects

The toxicity of PCBs to animals was first noticed in the 1970s when emaciated seabird corpses with very high PCB body burdens were washed up on beaches. The sources of the PCBs were unknown though, because seabirds may die at sea and be washed ashore from a very wide area. Where they were found was no reliable indicator of where they had died.

The toxicity of PCBs varies considerably among congeners. The coplanar PCBs, known as non-ortho PCBs because they are not substituted at the ring positions ortho to (next to) the other ring, (i.e. PCBs 77, 126, 169, etc), tend to have dioxin-like properties, and generally are among the most toxic congeners. Because PCBs are almost invariably found in complex mixtures, the concept of toxic equivalency factors (TEFs) has been developed to facilitate risk assessment and regulatory control, where more toxic PCB congeners are assigned higher TEF values. One of the most toxic compounds known, 2,3,7,8-tetrachlorodibenzo[p]dioxin, is assigned a TEF of 1. [12]

Signs and symptoms

  • Humans
The most commonly observed health effects in people exposed to PCBs are skin conditions such as chloracne and rashes, but these were known to be symptoms of systemic poisoning dating back to the 1920s. Studies in workers exposed to PCBs have shown changes in blood and urine that may indicate liver damage. In 1968 in Japan, PCB contamination in rice bran oil caused a mass poisoning known as Yushō Disease in over 14000 people.[13] Common symptoms included dermal and ocular lesions, irregular menstrual cycles and a lowered immune response.[14][15][16] Other symptoms included fatigue, headache, cough, and unusual skin sores.[17] Additionally, in children, there were reports of poor cognitive development.[14][16][17]
There have also been studies of the health effects of PCBs in the general population and in children of mothers who were exposed to PCBs.
  • Animals
Animals that eat PCB-contaminated food even for short periods of time get liver damage and may die. In 1968 in Japan, 400,000 birds died after eating poultry feed that was contaminated with PCBs.[13] Animals that eat smaller amounts of PCBs in food over several weeks or months develop various kinds of health effects, including anemia; acne-like skin conditions (chloracne); and liver, stomach, and thyroid gland injuries (including hepatocarcinoma). Other effects of PCBs in animals include changes in the immune system, behavioral alterations, and impaired reproduction. PCBs are not known to cause birth defects in humans, although those that have dioxin-like activity are known to cause a variety of teratogenic effects in animals.
  • Effects during pregnancy/breastfeeding
Women who were exposed to relatively high levels of PCBs in the workplace or ate large amounts of fish contaminated with PCBs had babies that weighed slightly less than babies from women who did not have these exposures. Babies born to women who ate PCB-contaminated fish also showed abnormal responses in tests of infant behavior. Some of these behaviors, such as problems with motor skills and a decrease in short-term memory, lasted for several years. Other studies suggest that the immune system was affected in children born to and nursed by mothers exposed to increased levels of PCBs. The most likely way infants will be exposed to PCBs is from breast milk. Transplacental transfers of PCBs were also reported.
Studies have shown that PCBs alter estrogen levels in the body and contribute to reproduction problems. In the womb, males can be feminized or the baby may be intersex, neither a male nor a female. Also, both sets of reproductive organs may develop. More instances of this are being reported. Biological magnification of PCBs has also led to polar bears and whales that have both male and female sex organs and males that cannot reproduce. This effect is also known as endocrine disruption. Endocrine Disrupting Chemicals (EDC's) pose a serious threat to reproduction in top-level predators.

Cancer link

A few studies of workers indicate that PCBs were associated with specific kinds of cancer in humans, such as cancer of the liver and biliary tract. Rats that ate food containing high levels of PCBs for two years developed liver cancer. The Department of Health and Human Services (DHHS) has concluded that PCBs may reasonably be anticipated to be carcinogens. The US Environmental Protection Agency (EPA) and the International Agency for Research on Cancer (IARC) have determined that PCBs are probably carcinogenic to humans. PCBs are also classified as probable human carcinogens by the National Cancer Institute, World Health Organization, and the Agency for Toxic Substances and Disease Registry. Recent research by the National Toxicology Program has confirmed that PCB126 (Technical Report 520) and a binary mixture of PCB126 and PCB153 (Technical Report 531) are carcinogens.

Mechanism of action

As discussed, PCBs exhibit a wide range of toxic effects. These effects may vary depending on the specific PCB. Similar to dioxin, toxicity of coplanar PCBs and mono-ortho-PCBs are thought to be primarily mediated via binding to aryl hydrocarbon receptor (AhR).[18][19] Because AhR is a transcription factor, abnormal activation may disrupt cell function by altering the transcription of genes. The concept of toxic equivalency factors (TEF) is based on the ability of a PCB to activate AhR.

However, not all effects may be mediated by the AhR receptor. For example, di-ortho-substituted non-coplanar PCBs interfere with intracellular signal transduction dependent on calcium; this may lead to neurotoxicity.[20] Ortho-PCBs may disrupt thyroid hormone transport by binding to transthyretin.[21]


Landfill – Large quantities of PCBs have been placed in landfill sites, mainly in the form of transformers and capacitors. Many municipal sites are not designed to contain these pollutants and PCBs are able to escape into the atmosphere or ground water. No emissions above background are seen if the landfill is designed correctly.

Methods of destruction

These can be separated into three distinct categories: physical, microbial, and chemical destruction.


Incineration – Although PCBs do not ignite themselves, they can be combusted under extreme and carefully controlled conditions. The current regulations require that PCBs are burnt at a temperature of 1200°C for at least two seconds, in the presence of fuel oil and excess oxygen. A lack of oxygen can result in the formation of PCDDs, PCDFs and dioxins, or the incomplete destruction of the PCBs. Such specific conditions mean that it is extremely expensive to destroy PCBs on a tonnage scale, and it can only be used on PCB containing equipment and contaminated liquid. This method is not suitable for the decontamination of affected soils.

Ultrasound – In a similar process to combustion, high power ultrasonic waves are applied to water, generating cavitation bubbles. These then implode or fragment, creating microregions of extreme pressures and temperatures where the PCBs are destroyed. Water is thought to undergo thermolysis, oxidising the PCBs to CO, CO2 and hydrocarbons such as biphenyl, with chlorine present as the inorganic ion 16. The scope of this method is limited to those congeners which are the most water soluble; those isomers with the least chlorine substitution.

Irradiation – If a deoxygenated mixture of PCBs in isopropanol or mineral oil is subject to irradiation with gamma rays then the PCBs will be dechlorinated to form inorganic chloride and biphenyl. The reaction works best in isopropanol if potassium hydroxide (caustic potash) is added. Solvated electrons are thought to be responsible for the reaction. If oxygen, nitrous oxide, sulfur hexafluoride or nitrobenzene is present in the mixture then the reaction rate is reduced. This work has been done recently in the US often with used nuclear fuel as the radiation source[1][2].


Much recent work has centered on the study of micro-organisms that are able to decompose PCBs. Generally, these organisms work in one of two ways: either they use the PCB as a carbon source, or destruction takes place through reductive dechlorination, with the replacement of chlorine with hydrogen on the biphenyl skeleton. However, there are significant problems with this approach. Firstly, these microbes tend to be highly selective in their dechlorination, with lower chlorinated biphenyls being readily transformed, and with preference to dechlorination in the para and meta positions. Secondly, microbial dechlorination tends to be rather slow acting on PCB as a soil contaminant in comparison to other methods. Finally, while microbes work well in laboratory conditions, there is often a problem in transferring a successful laboratory strain to a natural system. This is because the microbes can access other sources of carbon, which they decompose in preference to PCBs.

Further recent developments have focused on testing enzymes and vitamins extracted from microbes which show PCB activity. Especially promising seems to be the use of vitamin B12, in which a cobalt ion is in oxidation state (III) under normal redox conditions. Using titanium (III) citrate as a strong reductant converts the cobalt from Co(III) to Co(I), giving a new vitamin known as B12s, which is a powerful nucleophile and reducing catalyst. This can then be used on PCBs, which it dechlorinates in a rapid and selective manner.[22]


Many chemical methods are available to destroy or reduce the toxicity of PCBs.

Nucleophilic aromatic substitution is a method of destroying low concentration PCB mixtures in oils, such as transformer oil. Substitution of chlorine by polyethylene glycols) occurs in under two hours under a blanket of nitrogen, to prevent oxidation of the oil, to produce aryl polyglycols, which are insoluble in the oil and precipitate out.

Between 700 and 925°C, H2 cleaves the carbon-chlorine bond, and cleaves the biphenyl nucleus into benzene yielding HCl without a catalyst. This can be performed at lower temperatures with a copper catalyst, and to yield biphenyl. However, since both of these routes require an atmosphere of hydrogen gas and relatively high temperatures, they are prohibitively expensive.

Reaction with highly electropositive metals, or strong reducing agents such as sodium naphthalide, in aprotic solvents results in a transfer of electrons to the PCB, the expulsion of a chloride ion, and a coupling of the PCBs. This is analogous to the Wurtz reaction for coupling halogenoalkanes. The effect is to polymerise many molecules, therefore reducing the volatility, solubility and toxicity of the mixture. This methodology is most successful on low strength PCB mixtures and can also be performed electrochemically in a partly aqueous bicontinuous microemulsion.

The solution photochemistry of PCBs is based on the transfer of an electron to a photochemically excited PCB from a species such as an amine, to give a radical anion. This either expels a chloride ion and the resulting aryl radical extracts a hydrogen atom from the solvent, or immediately becomes protonated, leading to the loss of a chlorine atom. It is useful only for water soluble PCBs.

The major pathway for atmospheric destruction of PCBs is via attack by OH radicals. Direct photolysis can occur in the upper atmosphere, but the ultraviolet wavelengths necessary to excite PCBs are shielded from the troposphere by the ozone layer. It has, however, been shown that higher wavelengths of light (> 300 nm) can degrade PCBs in the presence of a photosensitizer, such as acetone.

The Schwartz reaction is the subject of much study, and has significant benefits over other routes. It is advantageous since it proceeds via a reductive process, and thus yields no dioxins through oxidation. The proposed reaction scheme involves the electron transfer from a titanium (III) organometallic species to form a radical anion on the PCB molecule which expels chlorine to eventually form the relatively non-toxic biphenyl.

See also

  • GE
  • Bay mud
  • Organochlorine compound
  • Polybrominated biphenyls
  • Neal Stephenson's novel Zodiac involves PCBs and their impact on the environment.


  1. ^ a b c d e f g h i j k Proceedings of the Subregional Awareness Raising Workshop on Persistent Organic Pollutants (POPs), Bangkok, Thailand. United Nations Environment Programme (November 25-28th, 1997). Retrieved on 2007-12-11.
  2. ^ a b UNEP Chemicals (1999). Guidelines for the Identification of PCBs and Materials Containing PCBs. United Nations Environment Programme, p.2. Retrieved on 2007-11-07. 
  3. ^ Amy Boate, Greg Deleersnyder, Jill Howarth, Anita Mirabelli, and Leanne Peck (2004). Chemistry of PCBs. Retrieved on 2007-11-07.
  4. ^ a b (1997) Identifying PCB-Containing Capacitors. Australian and New Zealand Environment and Conservation Council (ANZECC), pp.4-5. ISBN 0 642 54507 3. Retrieved on 2007-07-07. 
  5. ^ Karlyn Black Kaley, Jim Carlisle, David Siegel, Julio Salinas (October 2006). Health Concerns and Environmental Issues with PVC-Containing Building Materials in Green Buildings (pdf), Integrated Waste Management Board, California Environmental Protection Agency, USA, p.11. Retrieved on 2007-08-03. 
  6. ^ Brown, R. M. , Chemist-Analyst, 36, 33 (1947). | ChemPort
  7. ^ Breivik K, Sweetman A, Pacyna JM, Jones KC (2002). "Towards a global historical emission inventory for selected PCB congeners - a mass balance approach 1. Global production and consumption". The Science of the Total Environment 290: 181-198.
  8. ^ a b c d Hudson River PCBs — Background and Site Information. United States Environmental Protection Agency. Retrieved on 2007-12-31.
  9. ^ a b c d e Hudson River PCBs. United States Environmental Protection Agency (2007-06-27). Retrieved on 2007-12-31.
  10. ^ "Hudson River Virtual Tour — Chapter 9: PCB Pollution in the Hudson. New York State Department of Environmental Conservation. Retrieved on 2007-12-31.
  11. ^ Bette Hileman (1988-02-08). "The Great Lakes cleanup effort". Chemistry and Engineering 8: 22-39.
  12. ^ Van den Berg M, Environ Health Perspect. 1998 Dec;106(12):775-92
  13. ^ a b Contamination of rice bran oil with PCB used as the heating medium by leakage through penetration holes at the heating coil tube in deodorization chamber. Japan Science and Technology Agency. Retrieved on 2007-12-11.
  14. ^ a b
  15. ^ Disease ID 8326 at NIH's Office of Rare Diseases
  16. ^ a b
  17. ^ a b
  18. ^ Safe S (1984). "Polychlorinated biphenyls (PCBs) and polybrominated biphenyls (PBBs): biochemistry, toxicology, and mechanism of action". Crit. Rev. Toxicol. 13 (4): 319-95. PMID 6091997.
  19. ^ Safe S, Bandiera S, Sawyer T, Robertson L, Safe L, Parkinson A, Thomas PE, Ryan DE, Reik LM, Levin W (1985). "PCBs: structure-function relationships and mechanism of action". Environ. Health Perspect. 60: 47-56. PMID 2992927.
  20. ^ Simon T, Britt JK, James RC (2007). "Development of a neurotoxic equivalence scheme of relative potency for assessing the risk of PCB mixtures". PMID 17475378.
  21. ^ Chauhan KR, Kodavanti PR, McKinney JD (2000). "Assessing the role of ortho-substitution on polychlorinated biphenyl binding to transthyretin, a thyroxine transport protein". Toxicol. Appl. Pharmacol. 162 (1): 10-21. PMID 10631123.
  22. ^ Woods SL, Trobaugh DJ (1999). "Polychlorinated Biphenyl Reductive Dechlorination by Vitamin B12s: Thermodynamics and Regiospecificity". Environ. Sci. Technol. 33: 857-863.


PCB homolog table

For a complete list of PCB congeners, see PCB Congener List. Note that biphenyl, while not technically a PCB congener due to its lack of chlorine substituents, is still typically included in the literature.

PCB Homolog CASRN Cl Substituents Number of Congeners
Biphenyl 92-52-4 0 1
Monochlorobiphenyl 27323-18-8 1 3
Dichlorobiphenyl 25512-42-9 2 12
Trichlorobiphenyl 25323-68-6 3 24
Tetrachlorobiphenyl 26914-33-0 4 42
Pentachlorobiphenyl 25429-29-2 5 46
Hexachlorobiphenyl 26601-64-9 6 42
Heptachlorobiphenyl 28655-71-2 7 24
Octachlorobiphenyl 55722-26-4 8 12
Nonachlorobiphenyl 53742-07-7 9 3
Decachlorobiphenyl 2051-24-3 10 1
This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Polychlorinated_biphenyl". A list of authors is available in Wikipedia.
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