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Calcium acetate

IUPAC name

Calcium acetate

Other names

Acetate of lime
Calcium ethanoate

Identifiers

Abbreviations

Ca(OAc)₂

CAS number

62-54-4

SMILES

CC([O-)]=O.CC([O-])=O.[Ca++]

Properties

Molecular formula

C₄H₆O₄Ca

Molar mass

158.138 g/mol

Appearance

White solid

Density

1.6 kg/L

Melting point

160 °C (decomposition to acetone)

Solubility in water

400 g/l

Hazards

NFPA 704

Autoignition
temperature

680 - 730 °C

Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)
Infobox disclaimer and references

The chemical compound calcium acetate is the calcium salt of acetic acid. It has the formula Ca(C₂H₃O₂)₂. Its standard name is calcium acetate, while calcium ethanoate is the systematic IUPAC name. An older name is acetate of lime. The anhydrous form is very hygroscopic; therefore the monohydrate (Ca(CH₃COO)₂.H₂O, CAS [5743-26-0]) is the common form.

Additional recommended knowledge

Daily Visual Balance Check

Daily Sensitivity Test

Weighing the right way

If an alcohol is added to a saturated solution of calcium acetate, a semisolid, flammable gel forms that is much like "canned heat" products such as Sterno. Chemistry teachers often prepare "California Snowballs", a mixture of calcium acetate solution and ethanol. The resulting gel is whitish in color, and can be formed to resemble a snowball.

History

Because it is inexpensive, calcium acetate was once a common starting material for the synthesis of acetone before the development of the cumene process.^[1] ^[2]

Uses

In kidney disease, blood levels of phosphate may rise (called hyperphosphatemia) leading to bone problems. Calcium acetate binds phosphate in the diet to lower blood phosphate levels. Side effects of this treatment include upset stomach.

It is a food additive, mainly in candy products, though its purpose is unclear.

References

^ Leo Frank Goodwin and Edward Tyghe Sterne (1920). "Losses Incurred in the Preparation of Acetone by the Distillation of Acetate of Lime.". Industrial & Engineering Chemistry 12 (3): 240 - 243. doi:10.1021/ie50123a012.
^ E. G. R. Ardagh, A. D. Bbarbour, G. E. McClellan, and E. W. McBride (1924). "Distillation of Acetate of Lime.". Industrial & Engineering Chemistry 16 (11): 1133 - 1139. doi:10.1021/ie50179a013.