My watch list  

Enzymatic synthesis of lignin‐siloxane hybrid functional polymers


This study combines the properties of siloxanes and lignin polymers to produce hybrid functional polymers that can be used as adhesives, coating materials, and/or multifunctionalized thin‐coating films. Lignin‐silica hybrid copolymers were synthesized by using a sol‐gel process. Laccases from Trametes hirsuta were used to oxidize lignosulphonates to enhance their reactivity towards siloxanes and then were incorporated into siloxane precursors undergoing a sol‐gel process. In vitro copolymerization studies using pure lignin monomers with aminosilanes or ethoxytrimethylsilane and analysis by 29Si NMR spectroscopy revealed hybrid products. Except for kraft lignin, an increase in lignin concentration positively affected the tensile strength in all samples. Similarly, the viscosity generally increased in all samples with increasing lignin concentration and also affected the curing time.

Authors:   Endry Nugroho Prasetyo; Tukayi Kudanga; Roman Fischer; Reinhard Eichinger; Gibson S. Nyanhongo; Georg M. Guebitz; E. Nugroho Prasetyo; T. Kudanga; R. Fischer; R. Eichinger; G.S. Nyanhongo; G.M. Guebitz
Journal:   Biotechnology Journal
Year:   2011
Pages:   n/a
DOI:   10.1002/biot.201100106
Publication date:   11-Jul-2011
Facts, background information, dossiers
  • copolymers
  • adhesives
More about Wiley
Your browser is not current. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE