Order and fluidity often coexist, with examples ranging from biological membranes to liquid crystals, but the symmetry of these soft-matter systems is typically higher than that of the constituent building blocks. We dispersed micrometer-long inorganic colloidal rods in a nematic liquid crystalline fluid of molecular rods. Both types of uniaxial building blocks, while freely diffusing, interact to form an orthorhombic nematic fluid, in which like-sized rods are roughly parallel to each other and the molecular ordering direction is orthogonal to that of colloidal rods. A coarse-grained model explains the experimental temperature-concentration phase diagram with one biaxial and two uniaxial nematic phases, as well as the orientational distributions of rods. Displaying properties of biaxial optical crystals, these hybrid molecular-colloidal fluids can be switched by electric and magnetic fields.
Authors: |
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Haridas Mundoor; Sungoh Park; Bohdan Senyuk; Henricus H. Wensink; Ivan I. Smalyukh |
Journal: |
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Science
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Volume: |
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360 |
edition: |
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6390 |
Year: |
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2018 |
Pages: |
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768 |
DOI: |
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10.1126/science.aap9359
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Publication date: |
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18-May-2018 |